Selective hydrogenation of acetylene over Cu(211), Ag(211) and Au(211): Horiuti–Polanyi mechanism vs. non-Horiuti–Polanyi mechanism
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چکیده
منابع مشابه
Selective Hydrogenation of Acetylene over Palladium in Ultra High Vacuum
Under ultra-high-vacuum conditions, precoverage of a palladium(ll1) surface with hydrogen does not affect either the kinetics or the extent of acetylene uptake at 175 K. The subsequent reactive behavior of the system is however radically altered. Benzene formation is strongly suppressed, the transformation of adsorbed acetylene to another species (@-phase) is enhanced, and the yield of ethylene...
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Intermetallic compounds (IMCs) have shown excellent catalytic performance toward the selective hydrogenation of acetylene, but the theoretical understanding on this reaction over Ni-based IMCs is rather limited. In this work, the adsorptions of the C2 species, Bader charge, projected density of states (PDOS) and the reaction pathways were calculated by the density functional theory (DFT) method...
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A DFT + U study of acetylene selective hydrogenation over anatase supported PdaAgb (a + b = 4) cluster.
It is well known that the addition of Ag into Pd can promote the selectivity of acetylene hydrogenation to ethylene, and early theoretical studies focus on ideal single crystal model catalysts, so it is worth studying relatively realistic catalyst models, such as metal oxide supported PdAg systems. In this work, the reaction mechanisms for acetylene selective hydrogenation on the anatase TiO2(1...
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1-butyl-3-methyl imidazolinium hydroxide ionic liquid (BMIm[OH]) is loaded on commercial low surface area Pd-Ag/α-Al2O3 solid catalyst to enhance higher selectivity of acetylene partial hydrogenation. Different experimental techniques such as atomic absorption spectroscopy, surface area measurement and gas chromatography have been utilized to characterize chemical, structural and catalytic pro...
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ژورنال
عنوان ژورنال: Catalysis Science & Technology
سال: 2017
ISSN: 2044-4753,2044-4761
DOI: 10.1039/c6cy02587k